Calciner

VTT LaunchPad team developing solutions for industrial decarbonization.

Our focus is on thermochemical CO2 reduction, where CO2 containing gas stream can be converted into carbon monoxide rich synthesis gas.

Produced gas can be used in combustion based processes directly as eFuel, or it can be used as a feed at synthetic hydrocarbon production.


Our solutions

Calcination-based solutions

To combat climate change, we've developed an electricity-based method to produce carbon-neutral lime for cement and lime industries, which emits a clean and easily refinable carbon dioxide for utilization to eFuel, synthetic hydrocarbons and materials.

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Climate change is a huge problem we need to stop. One way to help is by making industries use electricity and produce goods without releasing carbon dioxide.

"Carbon-neutral" means making things without increasing atmospheric carbon dioxide level.

We have a method to produce carbon-neutral lime using electricity and carbon capture solutions, which allow for the capture of pure carbon dioxide, enabling its efficient utilization.

But, when making lime, carbon dioxide is produced. The good thing is, our method makes a clean carbon dioxide stream that's easy and cheap to refine.

Negative emissions

To combat climate change effectively, we must not only prevent new emissions but also repair past damages via using carbon-negative solutions like the lime cycle and Direct Air Capture (DAC), with ocean alkalization as an optimal storage method.

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To effectively fight climate change, we can't just stop new emissions. We also need to fix the damage already done by removing old emissions and healing nature.

"Carbon-negative" means solutions that remove more emissions than they create, reducing the amount of carbon dioxide in the air.

Our methods use the lime cycle to capture carbon dioxide from atmosphere. This cycle can capture double the carbon dioxide than what's produced during lime production.

The existing uses of lime contribute to carbon capture, as concrete undergoes carbonation during its use or at the end of its lifecycle, or when lime facilitates slag formation in the steel industry. These traditional applications inherently result in carbon capture.

A popular method is Direct Air Capture (DAC), which takes carbon directly from the air. Electric calcination is key in this.

The best way to store large amounts of carbon is by making the oceans more alkaline using eco-friendly lime. This also helps protect nature.

Reduction

Our method efficiently converts carbon dioxide into carbon monoxide, making renewable industries more cost-effective, increasing hydrogen yeld, and enabling affordable carbon capture while promoting renewable electricity-driven processes.

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Reduction is a process that turns carbon dioxide, a major climate change contributor, into carbon monoxide, useful for renewable industries.

Our new method makes producing synthetic hydrocarbons more cost-effective than traditional RWGS based process or direct CO2 utilization.

We can produce fuel gas powered by renewable electricity. This helps retrofit existing industrial processes that can't be directly electrified, with our eCO- electrofuel solution

Our approach makes it affordable to produce materials for capturing carbon and restoring nature.


Frequently Asked Questions

Where carbon-neutral cement and lime is used?

Carbon-neutral lime can be used in the production of cement and the manufacture of burnt lime. In the cement industry, a calcinator can produce carbon-neutral feed for the actual clinkerization process, capturing the CO2 emissions from limestone for reuse.

 

For the lime industry, we can directly produce a finished product that meets industrial requirements. This product is utilized in various applications such as a slag former in steel production, make-up lime in the pulp mill's alkali cycle, as well as an adjuster for brick industry pH levels and a water purifier.

What is carbon-negative carbon dioxide?

Carbon-negative carbon dioxide is regular carbon dioxide from which various materials and fuels can be produced by reducing it to carbon monoxide and synthesizing it with green hydrogen into synthetic hydrocarbons.

 

Carbon negativity is achieved with the lime produced during the process, meaning that throughout the production lifecycle, more carbon dioxide can be removed from the atmosphere than was emitted during product manufacture.

 

With our methods, the synthetic fuels produced can genuinely remove carbon dioxide from the atmosphere. In other words, the more of these fuels are used, the more carbon dioxide is removed from the atmosphere.

How and why carbon dioxide can be reduced

To reduce carbon dioxide, a number of strategies and technologies can be employed. One of these involves the process of calcination, where carbonates are broken down into oxides and carbon dioxide at high temperatures. Specifically, when a carbonate is exposed to high temperatures, it decomposes into an oxide and releases carbon dioxide.

 

For example, the calcination of calcium carbonate (limestone) produces calcium oxide (lime) and carbon dioxide:

CaCO3 > CaO + CO2

 

Based on similar principles, carbon dioxide can be further split through thermochemical and catalytic reactions into carbon monoxide and oxygen. This approach enables us to obtain valuable carbon monoxide, which can then be utilized in the production of synthetic hydrocarbons.

CO2 > CO + O

 

By utilizing this method, we can avoid the traditional water-gas shift reaction, where precious hydrogen is oxidized to produce water, merely to convert carbon dioxide into carbon monoxide. In the water-gas shift reaction:

CO2 + H2 > CO + H2O

 

Bypassing this RWGS reaction, the valuable hydrogen can be conserved, which is crucial given the increasing demand for hydrogen in various applications.

 

In summary, converting carbon dioxide into valuable carbon monoxide through these reactions not only helps reduce CO2 levels but also provides a valuable resource for the production of synthetic hydrocarbons, promoting a circular carbon economy.

What means nature coservation measures and CDR

Nature conservation measures refer to methods aimed at restoring environmental damages and biodiversity loss caused by human activities. Some of the most significant impacts arise from soil acidification and particularly from the acidification and excessive nutrients in water bodies. Such issues have led to problems like oceanic dead zones suffering from oxygen depletion, where only algae thrive and other marine life struggles.

 

There are methodologies available to mitigate these damages, and this is where carbon-neutral lime plays a pivotal role. It can be used to restore the pH levels of water bodies and bind excess nutrients, phosphorus being one of the most concerning. By enhancing the quality of agricultural soil using lime, nutrient runoff can be reduced. As the soil's pH normalizes, plant growth and crop yields can improve.

 

CDR stands for Carbon Dioxide Removal, which is the process of extracting carbon dioxide from the atmosphere and storing it permanently. The cycle of lime plays a significant role in this as well. From carbon-neutral lime, bicarbonate or double carbonate can be produced. This means that lime can bind two molecules of carbon dioxide to itself. As a result, this method can sequester twice the amount of carbon dioxide at the end of its life cycle compared to the amount of carbon dioxide released during the production from limestone.


Electric rotary kiln

VTT have developed a clean, flexible, and more efficient alternative to traditional, emissions-heavy processes used in lime and cement production. Our electric kiln can replace fossil-fuel based solutions for calcination while allowing CO2 capture in the process. This can significantly reduce the carbon footprint of industries that are responsible for some of the highest carbon emissions levels globally

It’s exciting to see properties of CaO produced in the best experiment points are very near to product-grade burnt lime.

Erkka Uuttu, Energy Manager, Nordkalk

 

The raw meal of cement production was successfully treated in the trial runs to an intermediate product which is fully calcined but not yet reacted with silica, which is exactly what is wanted to achieve in calciner.

Mathias Frankenhaeuser, Technical Manager, Finnsementti


Contact us

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